RAID 0 (zero) is actually the performace one.
RAID 1 is to back data from one disk directly to another, and others are a combination of the above, other than JDOB, which is literally Just a Bunch Of Disks.
With that motherboard (I used to have one), you can connect the 2 HDDs to the RAID controller (use 2 seperate IDE cables) and connect you other devices (CD, DVD, etc) to the usual, regular IDE connectors.
Just for comparisons sake, I have a RAID 0 setup, with 2x 40GB WD 8mb drives, and 1 regular 100gb WD 8mb